Bibliographic data

Document EP000002845857A1 (Pages: 22)

Bibliographic data Document EP000002845857A1 (Pages: 22)
INID Criterion Field Contents
54 Title TI [DE] Verwendung von Cyclohexa-2,5-dien-1-yl-Silanen als Vorläufer für gasförmige Hydrosilane
[EN] Use of cyclohexa-2,5-dien-1-yl-silanes as precursors for gaseous hydrosilanes
[FR] Utilisation de cyclohexa-2,5-dien-1-yl-silanes comme précurseurs pour des hydrosilanes gazeux
71/73 Applicant/owner PA UNIV BERLIN TECH, DE
72 Inventor IN OESTREICH MARTIN PROF DR, DE ; SIMONNEAU ANTOINE DR, DE
22/96 Application date AD Sep 10, 2013
21 Application number AN 13183727
Country of application AC EP
Publication date PUB Mar 11, 2015
33
31
32		 Priority data PRC
PRN
PRD

51 IPC main class ICM C07F 7/08 (2006.01)
51 IPC secondary class ICS
IPC additional class ICA
IPC index class ICI
Cooperative patent classification CPC C07F 5/00
MCD main class MCM C07F 7/08 (2006.01)
MCD secondary class MCS
MCD additional class MCA
57 Abstract AB [EN] The invention relates to the use of cyclohexa-2,5-dien-1-yl-silanes of general formula I for generation of hydrosilanes in solution using a strong Lewis acid. This way, e.g., alkenes can be hydrosilylated in good yields using the cyclohexa-2,5-dien-1-yl-silanes of general formula I as transfer hydrosilylating agents in the presence of a strong Lewis acid as catalyst with concomitant formation of an arene solvent.
56 Cited documents identified in the search CT DE000010326577A1
US020070142632A1
56 Cited documents indicated by the applicant CT
56 Cited non-patent literature identified in the search CTNP ANTOINE SIMONNEAU ET AL: "3-Silylated Cyclohexa-1,4-dienes as Precursors for Gaseous Hydrosilanes: The B(C 6 F 5 ) 3 -Catalyzed Transfer Hydrosilylation of Alkenes", ANGEWANDTE CHEMIE INTERNATIONAL EDITION, vol. 52, no. 45, 17 September 2013 (2013-09-17), pages 11905 - 11907, XP055089282, ISSN: 1433-7851, DOI: 10.1002/anie.201305584 0;
COLIN EABORN ET AL: "Reduction of Aryltrimethylsilanes as a Synthetic Method. Part 1. Electrochemical Reduction", JOURNAL OF THE CHEMICAL SOCIETY, PERKIN TRANSACTIONS 1, 1 January 1974 (1974-01-01), pages 2055 - 2061, XP055089530, Retrieved from the Internet [retrieved on 20131121], DOI: 10.1039/p19740002055 0;
ISHIKAWA ET AL.: "Photochemically generated silicon carbon double-bonded intermediates : III. The reaction of p-tolylpentamethyldisilane with methanol and methanol-d1", JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 118, no. 2, 5 October 1976 (1976-10-05), pages 155 - 160, XP002716703 0;
RÉMY ANGELAUD ET AL: "Desymmetrization of Cyclohexadienylsilanes. Regio-, Diastereo-, and Enantioselective Access to Sugar Mimics", THE JOURNAL OF ORGANIC CHEMISTRY, vol. 64, no. 26, 1 December 1999 (1999-12-01), pages 9613 - 9624, XP055089095, ISSN: 0022-3263, DOI: 10.1021/jo991225z 0;
STEPHAN AMREIN ET AL: "Radical Transfer Hydrosilylation/Cyclization Using Silylated Cyclohexadienes", ORGANIC LETTERS, vol. 3, no. 15, 1 July 2001 (2001-07-01), pages 2357 - 2360, XP055089270, ISSN: 1523-7060, DOI: 10.1021/ol016160c 0;
YANNICK LANDAIS ET AL: "Desymmetrization of Cyclohexa-1,4-dienes ? A Straightforward Route to Cyclic and Acyclic Polyhydroxylated Systems", EUR. J. ORG. CHEM., 1 January 2002 (2002-01-01), pages 4038 - 4052, XP055089093, Retrieved from the Internet 3.0.CO;2-3/asset/4037_ftp.pdf?v=1&t=ho744gq2&s=b9bc486275dc55bd3ea95d68bb34876cecb586c9> [retrieved on 20131119] 0;
SEBASTIAN RENDLER ET AL: "Schlüssiger Nachweis eines S N 2-Si-Mechanismus in der B(C6F5)3 - katalysierten Hydrosilylierung von Carbonylverbindungen: Einsichten in die verwandte Hydrierung", ANGEWANDTE CHEMIE (INTERNATIONAL ED. IN ENGLISH), vol. 120, no. 32, 28 July 2008 (2008-07-28), pages 6086 - 6089, XP055089418, ISSN: 0044-8249, DOI: 10.1002/ange.200801675 0
56 Cited non-patent literature indicated by the applicant CTNP
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